In situ powder neutron diffraction study of non-stoichiometric phase formation during the hydrogenation of Li3N.
نویسندگان
چکیده
The hydrogenation of Li3N at low chemical potential has been studied in situ by time-of-flight powder neutron diffraction and the formation of a non-stoichiometric Li4-2xNH phase and Li4NH observed. The results are interpreted in terms of a model for the reaction pathway involving the production of Li4NH and Li2NH, which subsequently react together to form Li4-2xNH. Possible mechanisms for the production of Li4NH from the hydrogenation of Li3N are discussed.
منابع مشابه
Mechanochemistry of lithium nitride under hydrogen gas.
Hydrogen uptake during the mechanochemistry of lithium nitride under 9 MPa hydrogen pressure has been analyzed by means of in situ solid-gas absorption and ex situ X-ray diffraction (XRD) measurements. In situ hydrogenation curves show two H-sorption steps leading to an overall hydrogen uptake of 9.8 wt% H after 3 hours of milling. The milled end-products consist of nanocrystalline (∼10 nm) LiN...
متن کاملAn in situ powder diffraction study of the structural mixed-phase of YBa2Cu3O6+x at 200 and 300C
In this study, the YBa2Cu3O6+x samples at temperatures 200 and 300°C, as the value of x ( the oxygen content in 0the basal plane) increased under nearly thermodynamical equilibrium condition, the structure changed from the well- known tetragonal (T) to a mixed-phase (T+OII) region (orthorhombicII phase is a superstructure). This mixed-phase region suggests a first order T/OII phase transition ...
متن کاملIn-situ HRPD study of superstructure OII phase in polycrystalline samples of YBCOx at 300 ºC
Superstructure orthorhombicII (OII) phase in polycrystalline samples of YBCOx was observed by using synchrotron in-situ high resolution powder diffraction (HRPD) techniques at 300˚C. Rietveld method (RM) refinement was employed to analyse the collected diffraction data under proper oxygen partial pressure atmospheres. Our study indicates that by oxygen uptake, the samples undergo structural pha...
متن کاملPalladium Gallium Intermetallic Compounds for the Selective Hydrogenation of Acetylene Part I: Preparation and Structural Investigation Under Reaction Conditions
15 August 2008 Abstract The intermetallic compounds PdGa and Pd3Ga7 are introduced as selective catalysts for the hydrogenation of acetylene. Single phase PdGa and Pd3Ga7 can readily be prepared by the appropriate thermal treatment of the stoichiometric mixtures of the corresponding elements. The initial low surface areas of the as-prepared materials can be increased by careful mechanical treat...
متن کاملLaNi5-Assisted Hydrogenation of MgNi2 in the Hybrid Structures of La1.09Mg1.91Ni9D9.5 and La0.91Mg2.09Ni9D9.4
This work focused on the high pressure PCT and in situ neutron powder diffraction studies of the LaMg2Ni9-H2 (D2) system at pressures up to 1,000 bar. LaMg2Ni9 alloy was prepared by a powder metallurgy route from the LaNi9 alloy precursor and Mg powder. Two La3−xMgxNi9 samples with slightly different La/Mg ratios were studied, La1.1Mg1.9Ni9 (sample 1) and La0.9Mg2.1Ni9 (sample 2). In situ neutr...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Faraday discussions
دوره 151 شماره
صفحات -
تاریخ انتشار 2011